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import requests

url = "https://api.hubapi.com/marketing/v4/email/single-send"

payload = "{\"customProperties\":{\"customProperty1\":\"value1\",\"customProperty2\":\"value2\"},\"emailId\":189490177320,\"message\":{\"cc\":[\"string\"],\"sendId\":\"string\",\"bcc\":[\"string\"],\"replyTo\":[\"****.com\"],\"from\":\"Test-sender\",\"to\":\"vitaliichao@medirect.com.au\"},\"contactProperties\":{\"lastname\":\"doe\",\"firstname\":\"john\"}}"
headers = {
    'accept': "application/json",
    'content-type': "application/json",
    'authorization': "Bearer pat-na1-*****"
    }

response = requests.request("POST", url, data=payload, headers=headers)

print(response.text)

{"statusId":"HDyC0WDUTSC8IGy8H_UpegAAAZaAcMruAtp3ZA==","requestedAt":"2025-04-29T07:26:38.018Z","status":"PENDING"}